A chemical survey of the Mississippi estuary     

Lewis E. Fox  Frederick Lipschultz  Lee Kerkhof  Steven C. Wofsy 《Estuaries and Coasts》1987,10(1):1-12

A “snap shot” survey of the Mississippi estuary was made during a period of low river discharge, when the estuarine mixing zone was within the deltaic channels. Concentrations of H⁺, Ca²⁺, inorganic phosphorus and inorganic carbon suggest that the waters of the river and the low salinity (<5‰) portion of the estuary are near saturation with respect to calcite and sedimentary calcium phosphate. An input of oxidized nitrogen species and N₂O was observed in the estuary between 0 and 4‰ salinity. The concentrations of dissolved NH₄ ⁺ and O₂, over most of the estuary, appeared to be influenced by decomposition of terrestrial organic matter in bottom sediments. The estuarine bottom also appears to be a source of CH₄ which has been suggested to originate from petroleum shipping and refining operations. Estuarine mixing with offshore Gulf waters was the dominant influence on distributions of dissolved species over most of the estuary (i.e., from salinities >5‰). The phytoplankton abundance (measured as chlorophylla) increased as the depth of the mixed layer decreased in a manner consistent with that expected for a light-limited ecosystem. Fluxes of NO₃ ^?+NO₂ ^? and soluble inorganic phosphorus to the Gulf of Mexico were estimated to be 3.4±0.2×10³ g N s^?1 and 1.9±0.2 g P s^?1 respectively, at the time of this study.  相似文献   

Carbonate chemistry in marine pore waters: MANOP sites C and S     

Steven Emerson  Varis Grundmanis  David Graham 《Earth and Planetary Science Letters》1982,61(2):220-232

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A revised identification of the oldest sea-floor spreading anomalies between Australia and Antarctica     

Steven C. Cande  John C. Mutter 《Earth and Planetary Science Letters》1982,58(2):151-160

We propose that magnetic anomalies south of Australia and along the conjugate margin of Antarctica that were originally identified as anomalies 19 to 22 may be anomalies 20 to 34. The original anomaly identification has two troublesome aspects: (1) it does not account for an “extra” anomaly between anomalies 20 and 21, and (2) it provides no explanation for the rough topography comprising the Diamantina Zone. With our revised identification there is no “extra” anomaly and the Diamantina Zone is attributed to a period of very slow spreading (～4.5mm/yr half rate) between 90 and 43 m.y. The ages bounding the interval of slow spreading (90 and 43 m.y.) correspond to times of global plate reorganizations. Our revised identification opens up the possibility that part of the magnetic quiet zone south of Australia formed during the Cretaceous long normal polarity interval. Breakup of Australia and Antarctica probably occurred sometime between 110 and 90 m.y. B.P. The “breakup unconformity” identified by Falvey in the Otway Basin may correspond to a eustastic sea level change.  相似文献   

Environmental oxidation rate of manganese(II): bacterial catalysis     

Steven Emerson  Susan Kalhorn  Lucinda Jacobs  Bradley M Tebo  Kenneth H Nealson  Reinhardt A Rosson 《Geochimica et cosmochimica acta》1982,46(6):1073-1079

A simple mass balance for dissolved manganese(II) in waters containing low levels of oxygen in Saanich Inlet indicates that the residence time for Mn(II) removal to the solid phase is on the order of a few days. The average oxidation state of Mn in particulate material sampled from the region of Mn removal was 2.3–2.7, and electron micrographs revealed structures characteristic of bacterially formed Mn precipitates. Radiotracer experiments utilizing ⁵⁴Mn(II) indicated that removal of Mn from solution in the region of active uptake was substantially blocked by a poison mixture, demonstrating that Mn(II) binding to particulates is catalyzed by bacteria in this environment.  相似文献   

The present day formation of apatite in Mexican continental margin sediments     

Richard A. Jahnke  Steven R. Emerson  Kevin K. Roe  William C. Burnett 《Geochimica et cosmochimica acta》1983,47(2):259-266

Results of pore water and sediment analyses from the western Mexican continental margin strongly suggest the present day formation of apatite. The interstitial water phosphate and fluoride profiles indicate chemical removal at a depth which corresponds to a large maximum in the phosphorus content of the sediments. Apatite is identified within this maximum via X-ray diffraction but is elsewhere undetectable in the core. Radioisotopic thorium, uranium, and radium data support the conclusion that this deposit is modern. The present day depositional environment is consistent with those reported by other workers for phosphorite formation with the exception that pore water magnesium is not depleted below its seawater value.  相似文献   

ENCORE: the effect of nutrient enrichment on coral reefs. Synthesis of results and conclusions   总被引：10，自引：0，他引：10  

Koop K  Booth D  Broadbent A  Brodie J  Bucher D  Capone D  Coll J  Dennison W  Erdmann M  Harrison P  Hoegh-Guldberg O  Hutchings P  Jones GB  Larkum AW  O'Neil J  Steven A  Tentori E  Ward S  Williamson J  Yellowlees D 《Marine pollution bulletin》2001,42(2):91-120

Coral reef degradation resulting from nutrient enrichment of coastal waters is of increasing global concern. Although effects of nutrients on coral reef organisms have been demonstrated in the laboratory, there is little direct evidence of nutrient effects on coral reef biota in situ. The ENCORE experiment investigated responses of coral reef organisms and processes to controlled additions of dissolved inorganic nitrogen (N) and/or phosphorus (P) on an offshore reef (One Tree Island) at the southern end of the Great Barrier Reef, Australia. A multi-disciplinary team assessed a variety of factors focusing on nutrient dynamics and biotic responses. A controlled and replicated experiment was conducted over two years using twelve small patch reefs ponded at low tide by a coral rim. Treatments included three control reefs (no nutrient addition) and three + N reefs (NH4Cl added), three + P reefs (KH2PO4 added), and three + N + P reefs. Nutrients were added as pulses at each low tide (ca twice per day) by remotely operated units. There were two phases of nutrient additions. During the initial, low-loading phase of the experiment nutrient pulses (mean dose = 11.5 microM NH4+; 2.3 microM PO4(-3)) rapidly declined, reaching near-background levels (mean = 0.9 microM NH4+; 0.5 microM PO4(-3)) within 2-3 h. A variety of biotic processes, assessed over a year during this initial nutrient loading phase, were not significantly affected, with the exception of coral reproduction, which was affected in all nutrient treatments. In Acropora longicyathus and A. aspera, fewer successfully developed embryos were formed, and in A. longicyathus fertilization rates and lipid levels decreased. In the second, high-loading, phase of ENCORE an increased nutrient dosage (mean dose = 36.2 microM NH4+; 5.1 microM PO4(-3)) declining to means of 11.3 microM NH4+ and 2.4 microM PO4(-3) at the end of low tide) was used for a further year, and a variety of significant biotic responses occurred. Encrusting algae incorporated virtually none of the added nutrients. Organisms containing endosymbiotic zooxanthellae (corals and giant clams) assimilated dissolved nutrients rapidly and were responsive to added nutrients. Coral mortality, not detected during the initial low-loading phase, became evident with increased nutrient dosage, particularly in Pocillopora damicornis. Nitrogen additions stunted coral growth, and phosphorus additions had a variable effect. Coral calcification rate and linear extension increased in the presence of added phosphorus but skeletal density was reduced, making corals more susceptible to breakage. Settlement of all coral larvae was reduced in nitrogen treatments, yet settlement of larvae from brooded species was enhanced in phosphorus treatments. Recruitment of stomatopods, benthic crustaceans living in coral rubble, was reduced in nitrogen and nitrogen plus phosphorus treatments. Grazing rates and reproductive effort of various fish species were not affected by the nutrient treatments. Microbial nitrogen transformations in sediments were responsive to nutrient loading with nitrogen fixation significantly increased in phosphorus treatments and denitrification increased in all treatments to which nitrogen had been added. Rates of bioerosion and grazing showed no significant effects of added nutrients. ENCORE has shown that reef organisms and processes investigated in situ were impacted by elevated nutrients. Impacts were dependent on dose level, whether nitrogen and/or phosphorus were elevated and were often species-specific. The impacts were generally sub-lethal and subtle and the treated reefs at the end of the experiment were visually similar to control reefs. Rapid nutrient uptake indicates that nutrient concentrations alone are not adequate to assess nutrient condition of reefs. Sensitive and quantifiable biological indicators need to be developed for coral reef ecosystems. The potential bioindicators identified in ENCORE should be tested in future research on coral reef/nutrient interactions. Synergistic and cumulative effects of elevated nutrients and other environmental parameters, comparative studies of intact vs. disturbed reefs, offshore vs. inshore reefs, or the ability of a nutrient-stressed reef to respond to natural disturbances require elucidation. An expanded understanding of coral reef responses to anthropogenic impacts is necessary, particularly regarding the subtle, sub-lethal effects detected in the ENCORE studies.  相似文献   

Reliability analysis of drilled shaft behavior using finite difference method and <Emphasis Type="Italic">Monte Carlo</Emphasis> simulation     

Anil Misra  Lance A. Roberts  Steven M. Levorson 《Geotechnical and Geological Engineering》2007,25(1):65-77

Load displacement analysis of drilled shafts can be accomplished by utilizing the “t-z” method, which models soil resistance along the length and tip of the drilled shaft as a series of springs. For non-linear soil springs, the governing differential equation that describes the soil-structure interaction may be discretized into a set of algebraic equations based upon finite difference methods. This system of algebraic equations may be solved to determine the load–displacement behavior of the drilled shaft when subjected to compression or pullout. By combining the finite difference method with Monte Carlo simulation techniques, a probabilistic load–displacement analysis can be conducted. The probabilistic analysis is advantageous compared to standard factor of safety design because uncertainties with the shaft–soil interface and tip properties can be independently quantified. This paper presents a reliability analysis of drilled shaft behavior by combining the finite difference technique for analyzing non-linear load–displacement behavior with Monte Carlo simulation method. As a result we develop probabilistic relationships for drilled shaft design for both total stress (undrained) and effective stress (drained) parameters. The results are presented in the form of factor of safety or resistance factors suitable for serviceability design of drilled shafts.  相似文献   

Science and Hollywood: a discussion of the scientific accuracy of <Emphasis Type="Italic">An Inconvenient</Emphasis><Emphasis Type="Italic">Truth</Emphasis>     

Steven M. Quiring 《GeoJournal》2007,68(1):1-3

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Electrical resistivity structure of the Valu Fa Ridge, Lau Basin, from marine controlled‐source electromagnetic sounding     

Lucy MacGregor  Martin Sinha  Steven Constable 《Geophysical Journal International》2001,146(1):217-236

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Investigating the ancient Martian magnetic field using microwaves   总被引：1，自引：0，他引：1  

John Shaw  Mimi J. Hill  Steven J. Openshaw 《Earth and Planetary Science Letters》2001,190(3-4):103-109

The new microwave palaeointensity technique has been used to investigate samples from the Martian meteorite Nakhla. This technique is a promising new way to obtain absolute palaeointensity information regarding the ancient Martian magnetic field as recorded by the Martian meteorites. Assuming that a part of the magnetic remanence is of thermal origin and originating on Mars the two samples studied yield estimates of 4 μT for the Martian magnetic field at 1.35 Ga.  相似文献